镧掺杂纳米二氧化钛透明光触媒乳液的制备及光催化性能

大气与环境光学学报 ›› 2013, Vol. 8 ›› Issue (6): 428-433.

镧掺杂纳米二氧化钛透明光触媒乳液的制备及光催化性能

张文明, 李玲*, 张华艳, 孙建红, 刘毅, 李晓苇, 傅广生

（河北大学物理科学与技术学院,河北省光电信息材料重点实验室, 河北保定 071002）

收稿日期:2013-07-19 修回日期:2013-09-02 出版日期:2013-11-28 发布日期:2013-11-06
通讯作者: 李玲（1980-），女，河北保定人，河北大学讲师，博士学位，主要从事纳米光催化材料的研究。 E-mail:lilinghbu@163.com
作者简介:张文明（1982-），男，吉林四平人，博士，讲师，主要从事可再生清洁能源的研究。
基金资助:
国家自然科学基金（21201053）、高等学校博士学科点专项科研基金（20121301120005）、河北省教育厅项目（Z2012044）、河北大学引进人才启动基金（2012-233）资助

Preparation and Photocatalytic Properties of Transparent La-Doped Titanium Dioxide Photocatalyst Emulsion

ZHANG Wen-ming, LI Ling, ZHANG Hua-yan, SUN Jian-hong, LIU Yi, LI Xiao-wei, FU Guang-sheng

(Hebei Key Laboratory of Optic-Electronic Information Materials, College of Physics Science and Technology，Baoding 071002，China)

Received:2013-07-19 Revised:2013-09-02 Published:2013-11-28 Online:2013-11-06

摘要/Abstract

摘要：

以四氯化钛、草酸、氨水、硝酸镧、D-山梨醇等为主要的实验药品，采用了常温络合—控制水解法，制备出平均粒径6.9 nm的镧掺杂纳米二氧化钛透明光触媒乳液。在太阳光照射下利用该透明乳液对酸性红3R染料降解，并研究了染料初始浓度、样品加入量、体系pH值、加热回流时间对降解效果的影响。采用XRD、纳米激光粒度分析仪、紫外—可见分光光度计等对样品的物相、粒径、组成、光吸收、光催化等性质进行了表征。结果表明，当镧掺杂量为0.1%、体系pH值为6、回流时间为10 min时，镧掺杂纳米二氧化钛光催化性能最好。太阳光照射60 min后，对浓度为25 mg/L的酸性红3R染料溶液的降解率达到98%以上。

关键词: 镧掺杂, 纳米TiO2, 透明光触媒乳液, 光催化

Abstract:

La-doped nano TiO2 colorless and transparent hydrosol with an average particle size of 6.9 nm was synthesized by a novel complexation-controlled hydrolysis method at room temperature by using TiCl4, organic carboxylic acid, stabilizer, surfactant, NH3•H2O, La(NO3)3•6H2O, and D-sorbitol etc as raw materials. And the acid red 3R was studied by the photocatalytic degradation. To study the effects of reflux time, pH and concentration and reaction conditions of the synthesis process and properties of the materials, the optimum preparation conditions were found out. The samples were characterized by X-ray diffraction (XRD), UV - visible spectroscopy (UV-Vis), and nano particle size analyzer. The La-doped nano-TiO2 transparent photocatalyst exhibits optimal photocatalytic performance when the doping content was 0.1% and the refluxing time was 10 min, respectively. The degradation efficiency of acid red 3R dye solution with concentration 25 mg/L has reached 98% after being exposed to sunlight for 60 min.

Key words: La doping, nano-TiO2, transparent photocatalyst emulsion, photocatalytic

中图分类号:

TB33
O64

张文明李玲张华艳孙建红刘毅李晓苇傅广生. 镧掺杂纳米二氧化钛透明光触媒乳液的制备及光催化性能[J]. 大气与环境光学学报, 2013, 8(6): 428-433.

ZHANG Wen-Ming, LI Ling, ZHANG Hua-Yan, SUN Jian-Hong, LIU Yi, LI Xiao-Wei, FU Guang-Sheng. Preparation and Photocatalytic Properties of Transparent La-Doped Titanium Dioxide Photocatalyst Emulsion[J]. Journal of Atmospheric and Environmental Optics, 2013, 8(6): 428-433.

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