大气碘化学与含碘气溶胶形成机制的研究进展

大气与环境光学学报 ›› 2018, Vol. 13 ›› Issue (1): 1-19.

• 综述 • 下一篇

大气碘化学与含碘气溶胶形成机制的研究进展

韦娜娜1,2，胡长进2，周闪闪2,3，马乔2,3，盖艳波2，林晓晓2，顾学军2，唐小锋2，方波2，赵卫雄2，张为俊2,4，吴代赦5

(1 安徽大学物理与材料科学学院，安徽合肥 230601；
2 中国科学院安徽光学精密机械研究所大气物理化学研究室，安徽合肥 230031；
3 中国科学技术大学研究生院，安徽合肥 230026；
4 中国科学技术大学环境科学与光电技术学院，安徽合肥 230026；
5 南昌大学资源环境与化工学院鄱阳湖环境与资源利用教育部重点实验室，江西南昌330031)

收稿日期:2016-12-31 修回日期:2017-01-16 出版日期:2018-01-28 发布日期:2018-02-06
通讯作者: 韦娜娜（1990-），女，安徽淮南人，硕士研究生，主要从事气溶胶烟雾箱方面的研究。 E-mail:761379182@qq.com
作者简介:韦娜娜（1990-），女，安徽淮南人，硕士研究生，主要从事气溶胶烟雾箱方面的研究。
基金资助:
Supported by Joint Funds of the National Natural Science Foundation of China(国家自然科学基金委员会–中国科学院大科学装置科学研究联合基金, U1532143,U1232209), National Natural Science Foundation of China(国家自然科学基金, 41575126，41363006)

Research Process on Atmospheric Chemistry of Iodine and Formation of Iodine Oxide Particles

WEI Nana1,2, HU Changjin2, ZHOU Shanshan2,3, Ma Qiao2,3, GAI Yanbo2, LIN Xiaoxiao2, GU Xuejun2, TANG Xiaofeng2, Fang Bo2, ZHAO Weixiong2, ZHANG Weijun2,4, WU Daishe5

(1 School of Physics and Materials Science, Anhui University, Hefei 230601, China;
2 Laboratory of Atmospheric Physico-Chemistry, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China;
3 Graduate School, University of Science and Technology of China, Hefei 230026, China;
4 School of Environmental Science and Optoelectronic Technology, University of Science and Technology of China, Hefei 230026, China; 5 Key Laboratory of Poyang Lake Environment and Resource Utilization, Ministry of Education, School of Resources Environmental and Chemical Engineering, Nanchang University, Nanchang 330031, China)

Received:2016-12-31 Revised:2017-01-16 Published:2018-01-28 Online:2018-02-06
About author:韦娜娜（1990-），女，安徽淮南人，硕士研究生，主要从事气溶胶烟雾箱方面的研究。
Supported by:
Supported by Joint Funds of the National Natural Science Foundation of China(国家自然科学基金委员会–中国科学院大科学装置科学研究联合基金, U1532143,U1232209), National Natural Science Foundation of China(国家自然科学基金, 41575126，41363006)

摘要/Abstract

摘要：

含碘气溶胶对全球气候与环境变化有着深远的影响。已有的研究表明含碘气溶胶的形成和生长源于含碘前体物（碘及碘化物）的氧化和后续聚合过程，含碘前体物的初步氧化会形成IO、OIO等具有高度反应活性的初级碘氧化物，进一步的氧化反应产生更稳定的碘氧化物IxOy,再经过后续聚合反应形成碘氧粒子(iodine oxide particles, IOPs)。IOPs的形成机制决定了含碘气溶胶的物化特性，最终决定了环境与气候效应。然而，现有的模型研究与大气观测结果之间，甚至是不同模型研究之间常常存在分歧，这些分歧又进而导致人们在评估含碘气溶胶对全球环境和气候变化影响效应上的不确定性。详细介绍了近年来大气碘化学与含碘气溶胶形成机制的研究进展，并指出了亟待解决的问题和面临的挑战。

关键词: 含碘前体物, I碘氧化物, 碘氧粒子, 环境气候效应

Abstract:

Photolysis of iodine and iodine compound in the presence of O3 has been proposed as a mechanism leading to intense iodine oxide particles (IOPs) formation, which has a profound influence on global climate change and atmospheric environment. It is believed that the formation of IOPs is involved with the production and oxidation of a series of iodine oxides (IxOy). However, the details of IOPs formation are not yet resolved, and there are still important gaps between modeling and field research, or even between different modeling work, which hinders precise evaluation of IOPs' impaction atmospheric processes, climate and human health. The main progress research on the formation of iodine oxide particles has been described and the major challenges have been discussed.

Key words: source of iodine, iodine oxides, iodine oxide particles, environment and climate effect

中图分类号:

X513

韦娜娜胡长进周闪闪马乔盖艳波林晓晓顾学军唐小锋方波赵卫雄张为俊吴代赦. 大气碘化学与含碘气溶胶形成机制的研究进展[J]. 大气与环境光学学报, 2018, 13(1): 1-19.

WEI Na-Na, HU Chang-Jin, ZHOU Shan-Shan, MA Qiao, GAI Yan-Bo, LIN Xiao-Xiao, GU Xue-Jun, TANG Xiao-Feng, FANG Bo, ZHAO Wei-Xiong, ZHANG Wei-Jun, WU Dai-She. Research Process on Atmospheric Chemistry of Iodine and Formation of Iodine Oxide Particles[J]. Journal of Atmospheric and Environmental Optics, 2018, 13(1): 1-19.

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大气碘化学与含碘气溶胶形成机制的研究进展

Research Process on Atmospheric Chemistry of Iodine and Formation of Iodine Oxide Particles

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