大气与环境光学学报 ›› 2025, Vol. 20 ›› Issue (1): 69-81.doi: 10.3969/j.issn.1673-6141.2025.01.006

• 环境光学监测技术 • 上一篇    下一篇

广德市大气中挥发性有机物的监测及环境影响分析

朱森 , 汪水兵 *, 秦志勇 , 卫尤文   

  1. 安徽省生态环境科学研究院, 安徽 合肥 230071
  • 收稿日期:2023-01-28 修回日期:2023-04-07 出版日期:2025-01-28 发布日期:2025-02-10
  • 通讯作者: E-mail: 252075663@qq.com E-mail:shbwang2006@163.com
  • 作者简介:朱森 (1983- ), 安徽淮北人, 工程师, 主要从事大气环境监测研究。E-mail: eiasen@126.com
  • 基金资助:
    安徽省博士后研究基金

Monitoring and environmental impact analysis of volatile organic compounds in atmosphere of Guangde City

ZHU Sen , WANG Shuibing* , QIN Zhiyong , WEI Youwen   

  1. Anhui Provincial Academy of Eco-Environmental Science Research, Hefei 230071, China
  • Received:2023-01-28 Revised:2023-04-07 Online:2025-01-28 Published:2025-02-10
  • Contact: Shuibing-Wang E-mail:shbwang2006@163.com
  • Supported by:
    Anhui Province Postdoctoral Research Fund Project

摘要: 运用多通道在线GC-MS/FID 在2021 年4―8 月对广德市工业园区和城镇生活区环境空气中的挥发性有机物 (VOCs) 分别进行了短期的连续监测, 研究了VOCs的浓度变化、组成特征、对臭氧生成潜势的贡献以及主要来源。结 果表明监测期间两个监测点共检出115 种VOCs, 总挥发性有机物 (TVOCs) 的平均体积分数分别为 (115.13 ± 49.58) × 10-9和 (132.97 ± 26.66) × 10-9, 其中VOCs含量排名前三的物种为芳香烃、烷烃和卤代烃。进一步的正定矩阵因子分解 (PMF) 模型分析表明, 两个监测点VOCs的主要来源略有差异, 其中工业园区监测点主要来源于溶剂使用、工业排放、 植物排放、机动车尾气、燃烧源和液化石油气 (LPG) 挥发, 城镇生活区监测点主要来源于溶剂使用、工业排放、机动车 尾气、LPG挥发和植物排放; 两个监测点排放的VOCs中都是芳香烃对臭氧生成潜势贡献最大。

关键词: 挥发性有机物, 污染特征, 来源解析, 臭氧生成潜势

Abstract: Multi-channel online GC-MS/FID was used to conduct short-term continuous monitoring of volatile organic compounds (VOCs) in the ambient air of industrial parks and urban living quarters in Guangde City, southeast of Anhui Province, China, from April to August 2021. And the concentration change, composition characteristics, contribution to ozone generation potential and main sources of VOCs in the two typical monitoring sites were studied. The results showed that a total of 115 kinds of VOCs were detected in the two monitoring sites during the monitoring period, and the average volume fraction of total VOCs (TVOCs) was (115.13 ± 49.58) × 10-9 and (132.97 ± 26.66) × 10-9, respectively. Among the TVOCs detected, the top three species were aromatic hydrocarbons, alkanes and halogenated hydrocarbons. Further analysis of the positive matrix factorization (PMF) model showed that the main sources of VOCs at the two monitoring sites were slightly different. VOCs in the industrial park were mainly from solvent use, industrial emissions, plant emissions, vehicle exhaust, combustion sources, and liquefied petroleum gas (LPG) volatilization, while those in urban living areas mainly came from solvent use, industrial emissions, vehicle exhaust, LPG volatilization, and plant emissions. Specifically, among the VOCs emitted, aromatic hydrocarbons contributed the most to ozone generation potential in both monitoring sites.

Key words: volatile organic compounds, pollution characteristics, source analysis, ozone formation potential

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