Detection of Disinfection By-Products in Tap Water by Solid Phase Microextraction Gas Chromatography Triple Quadrupole Mass Spectrometry

Journal of Atmospheric and Environmental Optics ›› 2017, Vol. 12 ›› Issue (4): 276-282.

Previous Articles Next Articles

Detection of Disinfection By-Products in Tap Water by Solid Phase Microextraction Gas Chromatography Triple Quadrupole Mass Spectrometry

KANG Meng1,2, ZOU Xue1, CAO Jinghao1, WANG Hongmei2, SHEN Chengyin1*, CHU Yannan1

(1 Anhui Province Key Laboratory of Medical Physics and Technology, Center of Medical Physics and Technology, Hefei Institutes of Physical Science, Chinese Academy of Science, Hefei 230031, China;
2 Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Science, Hefei 230031, China)

Received:2016-03-21 Revised:2016-03-31 Online:2017-07-28 Published:2017-07-19
Supported by:
Supported by Natural Science Foundation of China(国家自然科学基金, 21577145, 21477132)

Abstract

Abstract:

Solid phase microextraction gas chromatography triple quadrupole mass spectrometry (SPME-GC-TQMS) was used to detect the tap water from different areas in Hefei Science Island. It was used to study the existence of partial disinfection by-products (DBPs) in tap water and the relation between DBPs concentration and storage time of tap water in tube. SPME-GC-TQMS was also used to investigate the effectiveness of boiling method for the removal of halogen hydrocarbon disinfection byproduct. The results indicated that tap water in the Science Island contained chloroform, bromodichloromethane, dibromochloromethane and other halogenated hydrocarbon DBPs. In addition, their difference of concentration in tap water from different buildings was up to three times. The longer the storage time of tap water, the lower the concentration of DBPs. The results indicated that most of DBPs in tap water can be effectively removed after boiled. But the chloroform concentration only decreased to 30.2% of the original concentration of tap water.

Key words: disinfection by-products, solid phase microextraction gas chromatography triple quadrupole mass spectrometry, tap water

CLC Number:

O657

KANG Meng, ZOU Xue, CAO Jing-Hao, WANG Hong-Mei, SHEN Cheng-Yin, CHU Yan-Nan. Detection of Disinfection By-Products in Tap Water by Solid Phase Microextraction Gas Chromatography Triple Quadrupole Mass Spectrometry[J]. Journal of Atmospheric and Environmental Optics, 2017, 12(4): 276-282.

References

[1] Zhang Haiyan, Naren Gaowa, Song Caijun. Harm of disinfection by products in drinking water and its detection method [J]. Chinese Journal of Health Laboratory Technology, 2012, 22(3): 669-671(in Chinese).
张海燕, 娜仁高娃, 宋彩军. 生活饮用水中消毒副产物的危害及其检测方法探讨 [J]. 中国卫生检验杂志, 2012, 22(3): 669-671.
[2] Hrudey S E, Backer L C, Humpage A R, et al. Evaluating evidence for association of human bladder cancer with drinking water chlorination disinfection by products [J]. J. Toxicol. Env. Heal., 2015, 18(5): 213-241.
[3] Thorsby E. On the future of HLA [J]. Tissue Antigens, 2011, 78(4): 229-240.
[4] Zhao Jianli, Wang Long. Harmfulness and removal method of disinfection by-products of drinking water [J]. Water Sciences and Engineering Technology, 2008, 1(1): 51-54(in Chinese).
赵建莉, 王龙. 饮用水消毒副产物的危害及去除途径 [J]. 水科学与工程技术, 2008, 1(1): 51-54.
[5] Philip C S. Control of disinfection by- product in drinking water [J]. Water Environ. Res., 1998, 70(4): 27-34.
[6]Richardson S D, Fasano F, Ellington J J. Occurrence and mammalian cell toxicity of iodinated disinfection byproducts in drinking water [J]. Environ. Sci. Technol., 2008, 42(22): 8330-8338.
[7] Fan Aiping, Zhang Hongfei, Ou Weiping. Study on the influencing factors of headspace gas chromatography in the determination of trichloromethane in drink water after chlorine disinfection [J]. China Journal of Health Laboratory Technology, 2016, 26(1): 35-39(in Chinese).
范爱萍, 张虹飞, 欧维平. 顶空气相色谱法测定液氯消毒饮用水中三氯甲烷的影响因素研究 [J].中国卫生检验杂志, 2016, 26(1): 35-39.
[8] Yu Shengbing, Yu Binghui, Liu Jing. Determination of 11 kinds of volatile organic compounds in drinking water by headspace gas chromatography [J]. Occupation and Health, 2013, 29(1): 12-15(in Chinese).
余胜兵, 余炳辉, 刘静. 饮用水中11 种挥发性有机物的顶空-气相色谱测定法 [J]. 职业与健康, 2013, 29(1) : 12-15.
[9] Sun Shiping, Xing Darong, Duan Jiangping. Determination of 11 kinds of VOCs in drinking water with headspace gas chromatography [J]. Journal of Environment and Health, 2007, 24(8): 630-632(in Chinese).
孙仕萍, 邢大荣, 段江平. 饮用水中11 种挥发性有机物的顶空气相色谱测定法 [J]. 环境与健康杂志, 2007, 24(8): 630-632.
[10] Chen Guozheng, Xu Wei, Lin Yi. Determination of volatile chlorinated disinfection by-products in drinking water by purge and trap－GC/MS [J]. Chinese Journal of Health Laboratory Technology, 2012, 22(9): 2068-2071(in Chinese).
陈国征, 徐伟, 林怡. 吹扫捕集－气相色谱/质谱法测定饮用水中挥发性氯化消毒副产物 [J]. 中国卫生检验杂志, 2012, 22(9): 2068-2071.
[11] Zhang Yanping, Xiao Bing, Ding Guoqing. Determination of 15 volatile halogenated hydrocarbons in drinking water by purge-and-trap gas chromatography [J]. Chinese Journal of Health Laboratory Technology, 2010, 20(9): 2187-2188(in Chinese).
张艳萍, 肖兵, 丁国清. 吹扫捕集气相色谱法测定饮用水中15种挥发性卤代烃的方法研究 [J]. 中国卫生检验杂志, 2010, 20(9): 2187-2188. [12]Wang Haiou, Chen Zhonglin, Zhang Xuejun. Study on analysis method of halomethanes by liquid-liquid extraction and gas chromatography in drinking water [J]. Journal of Harbin University of Commerce: Natural Sciences Edition, 2011, 27(3): 296-299(in Chinese).
王海鸥, 陈忠林, 张学军. 液液萃取气相色谱法测定水中三卤甲烷研究 [J]. 哈尔滨商业大学学报, 2011, 27(3): 296-299.
[13] Wei Jiangrong, Jiang Lijuan, Han Zhiyu. Detection method of DPBs in drinking water by liquid-liquid extraction gas chromatography [J]. Chinese Journal of Health Laboratory Technology, 2004, 14(5): 542-544(in Chinese).
魏建荣, 姜丽娟, 韩志宇. 液-液萃取气相色谱法测定饮用水中消毒副产物检测方法的研究 [J]. 中国卫生检验, 2004, 14(5): 542-544.

Detection of Disinfection By-Products in Tap Water by Solid Phase Microextraction Gas Chromatography Triple Quadrupole Mass Spectrometry

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 1

Recommended Articles

Metrics

Comments