大气与环境光学学报 ›› 2020, Vol. 15 ›› Issue (1): 2-12.
杜增丰1,3,张鑫1, 2, 3*,郑荣儿4
出版日期:
2020-01-28
发布日期:
2020-01-19
DU Zengfeng1,3, ZHANG Xin1, 2, 3*, ZHENG Ronger4
Published:
2020-01-28
Online:
2020-01-19
摘要: 拉曼光谱是一种分子指纹光谱,在物质成分识别和定量分析领域已得到广泛应用,近年来也逐渐应用于深海极端环境
的原位探测。回顾了激光拉曼光谱技术的发展历程,介绍了国内外已经研发的深海激光拉曼光谱探测系统,并着重介绍
了各系统在深海冷泉、热液等极端区域对喷口流体、沉积物孔隙水、自生碳酸盐岩、水合物等目标物的原位探测和
应用,最后总结了限制拉曼光谱技术在深海取得更多应用的因素,可以为拉曼光谱技术未来的发展提供参考。
中图分类号:
杜增丰, 张鑫, 郑荣儿. 拉曼光谱技术在深海原位探测中的研究进展[J]. 大气与环境光学学报, 2020, 15(1): 2-12.
[1] | Lu T{bfongxing, Lu Yiqun. Principle and Application of Laser Spectroscopy[M]. Hefei: Press of |
University of Science and Technology of China, 2009 (in Chinese). | |
陆同兴, 路轶群. 激光光谱技术原理及应用. 第2版 [M]. 合肥: 中国科学技术大学出版社,2009. | |
[2] | Du Zengfeng. Detection of Acid Radical Ions with DOCARS and LCOF-Raman |
System and Spectral | |
Analysis of Sediment Pore Water [D]. Qingdao: Doctoral Dissertation of Ocean | |
University of China, 2015 (in Chinese). | |
杜增丰. 基于DOCARS和LCOF-Raman的酸根离子探测和沉积物孔隙水的光谱分析 [D]. 青岛: 中国 | |
海洋大学博士论文, 2015. | |
[3] | Bohren C F, Huffman D R. Absorption and Scattering of Light by Small |
Particles [M]. New Jersey: John Wiley & Sons, 2008, 93-101. | |
[4] | Cox A J, DeWeerd A J, Linden J. An experiment to measure Mie and Rayleigh total |
scattering cross sections [J]. | |
American Journal of Physics, 2002, 70(6): 620-625. | |
[5] | Zhang Mingsheng. Laser Light Scattering Spectroscopy [M]. Beijing:Science Press, 2008 (in Chinese). |
张明生. 激光光散射谱学 [M]. 北京: 科学出版社, 2008. | |
[6] | Zhang Shulin. Raman Spectroscopy and Low Ninameter Semiconductors [M]. |
Beijing: Science Press, 2008 (in Chinese). | |
张树霖. 拉曼光谱学与低维纳米半导体 [M]. 北京: 科学出版社, 2008. | |
[7] | Gauglitz G, Vo-Dinh T. Handbook of Spectroscopy [M]. New Jersey: JohnWiley & Sons, 2006. |
[8] | Smith E, Dent G. Modern Raman Spectroscopy: a Practical Approach [M]. NewJersey: John Wiley & Sons, 2013. |
[9] | McCreery R L. Raman Spectroscopy for Chemical Analysis [M]. New Jersey: |
John Wiley & Sons, 2005. | |
[10] | Zhu Ziying, Gu Renao, Lu Tianhong. Application of Raman Spectroscopy inChemistry [M]. Shenyang: |
Northeastern University Press, 1998 (in Chinese). | |
朱自莹, 顾仁敖, 陆天虹. 拉曼光谱在化学中的应用 [M]. 沈阳: 东北大学出版社, 1998. | |
[11] | Colthup N. Introduction to Infrared and Raman Spectroscopy [M]. |
Amsterdam: Elsevier, 2012. | |
[12] | Grasselli J G, Bulkin B J. Analytical Raman Spectroscopy [M]. New Jersey:Wiley, 1991. |
[13] | Placzek G. Handbuch der Radiologie, edited by Marx E. [J]. Nature, 1934,6(2): 205. |
[14] | Pelletier M J. Analytical Applications of Raman Spectroscopy [M]. NewJersey: Wiley-Blackwell, 1999. |
[15] | Gallagher A, Brewer P G, Peltzer E T, et al. Searching for CO$_2$ inmarine seiment pore waters: |
Methods and detection limits using laser Raman spectroscopy [J]. In MBARIreport, 2012. | |
[16] | Dunk R M, Peltzer E T, Walz P M, et al. Seeing a deep ocean CO$_2$enrichment experiment in a |
new light: laser Raman detection of dissolved CO$_2$ in seawater [J].Environmental | |
Science & Technology, 2005, 39(24): 9630-9636. | |
[17] | Hutchinson E J, Shu D, Laplant F, et al. Measurement of fluid filmthickness on curved surfaces |
by Raman Spectroscopy [J]. Applied spectroscopy, 1995, 49(9): 1275-1278. | |
[18] | Kontoyannis C G, Bouropoulos N C, Koutsoukos P G. Use of Raman spectroscopy forthe quantitative analysis |
of calcium oxalate hydrates: application for the analysis of urinary stones | |
[J] | Applied Spectroscopy, 1997, 51(1): 64-67. |
[19] | Lu W, Chou I M, Burruss R C. Determination of methane concentrations in waterin equilibrium with sI methane |
hydrate in the absence of a vapor phase by in situ Raman spectroscopy[J]. Geochimica et Cosmochimica Acta, 2008, 72(2): 412-422. | |
[20] | Lu W, Chou I M, Burruss R C, et al. A unified equation for calculatingmethane vapor pressures |
in the CH$_4-$H$_2$O system with measured Raman shifts [J]. Geochimica etCosmochimica Acta, 2007, 71(16): 3969-3978. | |
[21] | Wang X, Wang X, Chou I M, et al. Properties of lithium under hydrothermalconditions revealed by in |
situ Raman spectroscopic characterization of Li$_2$O-SO$_3$-H$_2$O (D$_2$O) | |
systems at temperaturesup to 420℃ [J]. Chemical Geology, 2017, 451: 104-115. | |
[22] | Brewer P G, Malby G, Pasteris J D, et al. Development of a laser Ramanspectrometer for deep-ocean |
science [J]. Deep Sea Research Part I: Oceanographic Research Papers,2004, 51(5): 739-753. | |
[23] | Du Z, Li Y, Chen J, et al. Feasibility investigation on deep oceancompact autonomous Raman |
spectrometer developed for in-situ detection of acid radical ions [J]. | |
Chinese Journal of Oceanology and Limnology, 2015, 33(2): 545-550. | |
[24] | Zhang X, Du Z, Zheng R, et al. Development of a new deep-sea hybrid Raman |
insertion probe and its | |
application to the geochemistry of hydrothermal vent and cold seep fluids [J]. | |
Deep Sea Research Part I: Oceanographic Research Papers, 2017, 123:1-12. | |
[25] | Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Thesuccessful sea trial of the first UV |
laser Raman spectrometer for in situ detection in deep ocean [EB-OL].(2007-04-04) [2019-12-09]. | |
http://www.dicp.cas.cn/xwdt/kyjz/201811/t20181119$_-$5187722.html (inChinese). | |
中国科学院大连化学物理研究所. 我所研发7千米级深海探测紫外激光拉曼光谱仪获得海试成功 | |
[EB-OL]. (2007-04-04) [2019-12-09]. | |
http://www.dicp.cas.cn/xwdt/kyjz/201811/t20181119$_-$5187722.html. | |
[26] | Lehaitre M, Charlou J L, Donval J P, et al. Raman spectroscopy: New |
perspectives for in situ shallow or | |
deep ocean exploration [C]//Geophys. Res. Abstr. 2005, 7: 03032. | |
[27] | Schmidt H, Ha N B, Pfannkuche J, et al. Detection of PAHs in seawater |
using surface-enhanced Raman | |
scattering (SERS) [J]. Marine Pollution Bulletin, 2004, 49(3): 229-234. | |
[28] | Paull C K, Hecker B, Commeau R, et al. Biological communities at theFlorida Escarpment resemble |
hydrothermal vent taxa [J]. Science, 1984, 226(4677): 965-967. | |
[29] | Levin L A, Baco A R, Bowden D A, et al. Hydrothermal vents and methaneseeps: rethinking the sphere of |
influence [J]. Frontiers in Marine Science, 2016, 3: 72. | |
[30] | Boetius A, Ravenschlag K, Schubert C J, et al. A marine microbialconsortium apparently mediating anaerobic |
oxidation of methane [J]. Nature, 2000, 407(6804): 623-626. | |
[31] | Niemann H, L"{osekann T, de Beer D, et al. Novel microbial communitiesof the Haakon Mosby mud volcano |
and their role as a methane sink [J]. Nature, 2006, 443(7113): 854-858. | |
[32] | Pasteris J, Wopenka B, Freeman J J, et al. Raman spectroscopy in the deepocean: successes and |
challenges [J]. Applied Spectroscopy, 2004, 58(7): 195A-208A. | |
[33] | White S N, Dunk R M, Peltzer E T, et al. In situ Raman analyses ofdeep-sea hydrothermal and cold seep |
systems (Gorda Ridge and Hydrate Ridge) [J]. Geochemistry GeophysicsGeosystems, 2006, 7(5): Q05023. | |
[34] | Zhang X, Walz P M, Kirkwood W J, et al. Development and deployment of a deep-sea Raman probe for |
measurement of pore water geochemistry [J]. Deep-Sea Research Part I: | |
Oceanographic Research Papers, 2010, 57(2): 297-306. | |
[35] | Zhang X, Hester K C, Ussler W, et al. In situ Raman-basedmeasurements of high dissolved methane concentrationsin hydrate-rich ocean sediments [J]. Geophysical Research Letters, 2011,38(38): 134-144. |
[36] | Xi Shichuan, Zhang Xin, DuZengfeng et al. A method based on Raman shift |
of sulfate for detection ofthe deep-sea hydrothermal fluid temperature [J]. Spectroscopy and Spectral | |
Analysis, 2018, 38(11): 76-80 (in Chinese). | |
席世川, 张~鑫, 杜增丰等. 硫酸根拉曼频移用于深海热液温度探测的方法探讨[J]. 光谱学与光谱 | |
分析, 2018, 38(11): 76-80. | |
[37] | Li L, Zhang X, Luan Z, et al. In situ quantitative Raman detectionof dissolved carbon dioxide and sulfate |
in deep-sea high-temperature hydrothermal vent fluids [J]. Geochemistry, | |
Geophysics, Geosystems, 2018, 19(6): 1809-1823. | |
[38] | Li L, Zhang X, Luan Z, et al. Raman vibrational spectral characteristicsand quantitative analysis |
of H$_2$ up to 400℃ and 40 MPa [J]. Journal of Raman Spectroscopy, 2018,49(10): 1722-1731. | |
[39] | Xi S, Zhang X, Luan Z, et al. A direct quantitative Raman method for themeasurement of dissolved |
bisulfate in acid-Sulfate fluids [J]. Applied Spectroscopy, 2018,72(8): 1234-1243. | |
[40] | Li L, Zhang X, Luan Z, et al. A new approach to measuring the temperatureof fluids reaching 300$^circ$ |
and 2 mol/kg NaCl based on the Raman shift of water [J]. AppliedSpectroscopy, 2018, 72(11): 1621-1631. | |
[41] | Du Z, Zhang X, Luan Z, et al. In situ Raman quantitative detectionof the cold seep vents and fluids |
in the chemosynthetic communities in the South China Sea [J].Geochemistry, Geophysics, Geosystems, 2018, 19(7): 2049-2061. | |
[42] | Fan F, Feng Z, Li C. UV Raman spectroscopic study on the synthesis mechanismand assembly of molecular |
sieves [J]. Chemical Society Reviews, 2010, 39(12): 4794-4801. | |
[43] | Kvenvolden K A. Gas hydrates—geological perspective and global change [J]. |
Reviews of Geophysics, 1993, 31(2): 173-187. | |
[44] | Lu H, Seo Y, Lee J, et al. Complex gas hydrate from the Cascadia margin[J]. Nature, 2007, 445(7125): 303-306. |
[45] | Sloan Jr E D. Fundamental principles and applications of natural gas hydrates[J]. Nature, 2003, 426(6964): 353-359. |
[46] | Fisher C R. Chemoautotrophic and methanotrophic symbioses in marineinvertebrates [J]. |
Reviews in Aquatic Sciences, 1990, 2: 399-436. | |
[47] | Du Z, Zhang X, Xi S, et al. In situ Raman spectroscopy study ofsynthetic gas hydrate formed by cold seepflow in the South China Sea [J]. Journal of Asian Earth Sciences, 2018,168: 197-206. |
[48] | Brewer P G, Orr F M, Friederich G, et al. Gas hydrate formation in thedeep sea: In situ experiments |
with controlled release of methane, natural gas, and carbon dioxide [J].Energy & Fuels, 1998, 12(1): 183-188. | |
[49] | Hester K C, Dunk R M, Walz P M, et al. Direct measurements of multi-component hydrates on the |
seafloor: pathways to growth [J]. Fluid Phase Equilibria, 2007, 261(1-2): 396-406. | |
[50] | Hester K C, White S N, Peltzer E T, et al. Raman spectroscopicmeasurements of synthetic gas hydrates in |
the ocean [J]. Marine Chemistry, 2006, 98(2-4): 304-314. | |
[51] | Hester K C, Dunk R M, White S N, et al. Gas hydrate measurements atHydrate Ridge using Raman |
spectroscopy [J]. Geochimica et Cosmochimica Acta, 2007, 71(12):2947-2959. | |
[52] | Zhang X, Du Z, Luan Z, et al. In situ Raman detection of gashydrates exposed on the seafloor of the |
South China Sea [J]. Geochemistry, Geophysics, Geosystems, 2017, 18(10): 3700-3713. | |
[53] | White S N. Laser Raman spectroscopy as a technique for identification ofseafloor hydrothermal and cold |
seep minerals [J]. Chemical Geology, 2009, 259(3-4): 240-252. | |
[54] | Xi S, Zhang X, Du Z, et al. Laser Raman detection of authigenic |
carbonates from cold seeps at theFormosa Ridge and east of the Pear River Mouth Basin in the South China Sea | |
[J] | Journal of Asian Earth Sciences, 2018, 168: 207-224. |
[1] | 郭金家, 卢渊, 李楠, 刘春昊, 田野, 薛博洋, 张超, 郑荣儿. LIBS水下原位探测技术研究进展[J]. 大气与环境光学学报, 2020, 15(1): 13-22. |
[2] | 闫静文 李颖 陈靓 杨德旺 郑荣儿. 基于最近邻比较和中值滤波的拉曼光谱spike自动检测及剔除方法研究[J]. 大气与环境光学学报, 2017, 12(2): 128-135. |
[3] | 杜增丰 杨德旺 王冰 张鑫 郑荣儿. 沉积物孔隙水的拉曼光谱探测及荧光时间演化特性[J]. 大气与环境光学学报, 2014, 9(6): 441-447. |
阅读次数 | ||||||
全文 |
|
|||||
摘要 |
|
|||||