Journal of Atmospheric and Environmental Optics ›› 2024, Vol. 19 ›› Issue (5): 580-588.

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Photoacoustic sensor based on broadband light source for ammonia detection

SUN Liuya , NIU Mingsheng *, CHEN Jiaxue , TANG Min , YIN Yajie , OUYANG Jinhua   

  1. Shandong Provincial Key Laboratory of Laser Polarization and Information Technology, Laser Research Institute, School of Physical Engineering, Qufu Normal University, Qufu 273165, China
  • Received:2022-02-21 Revised:2022-04-18 Online:2024-09-28 Published:2024-10-11

Abstract: High sensitivity of ammonia detection from different emission sources can provide certain reference for environmental management and medical diagnosis. However, current ammonia sensors have the disadvantages of weak absorption line of ammonia in the near infrared band, high cost of mid-infrared light source and generally large volume. A photoacoustic sensor based on broadband light source was proposed in this work. For this system, the selected working wavelength is around 2239 nm, where the line intensity of ammonia is 10-20 cm/molecule, which can effectively avoid the interference of CO2 and H2O. The results show that, the resonance frequency of the photoacoustic cell is 1830 Hz, the linear fitting of the measured signals of ammonia with different concentrations can reach 0.98976 under the conditions of room temperature, one atmosphere pressure and optical power of 2.46 mW, indicating the good linear response characteristic of the system, and Allan variance analysis show that the optimal integration time of the system is 100 s. It is shown that the developed sensor can meet the detection requirements of ammonia from different emission sources, and has important reference for realizing high sensitivity detection of ammonia.

Key words: gas sensor, photoacoustic spectroscopy, broadband light source, ammonia detection

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